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MIXSET.COM
MIXSET.COM started in 2002 to document sites on the web that offered mixed sets available for free. Sites listed on MIXSET.COM offer decent quality compressed format mix sets in may genre's.
breaksblog.biz
Always the freshed D&B on the net. Your number one resource for D&B mix sets.
hybridized.org
hybridized.org's goal is to contain as many high quality sets from our artists as possible while maintaining the full support of each artist. Featuring residents Alex Hall, Andrew Kelly, Benz & MD, Deepsky, Digital Witchcraft, Grayarea, Hybrid, Jason Dunne, Noel Sanger, NuBreed, Shiloh, Way Out West and many top name Guests, Hybridized.org won't dissapoint.
Blentwell
Run by the mysterious Mr. Blentwell, Blentwell.com uses a super duper linking system to document the latest and greatest online mixsets. Top genres include house, hip-hop, electro, funk and techno, with a lot of other genres also covered. Links go dead as time goes by, so visit regularly and grab the latests sets from around the world.
UMP3.DE
UMP3.DE has over 100 mix sets, some ripped straight from the radio however most are live sets from various clubs around the world. All their sets are encoded in high quality MP3 available to download from free download services like Megaupload and Megashares. All sets are dated between 2005 2006. Armand Van Helden, Carl Craig, Chemical Bros, Carl Cox, Deep Dish, Ian Pooly, James Holden, Laurent Garnier, The Prodigy and many many more.
MPIII.com
MPIII.com has hundreds of members interested in electronic music. The site is based on thousands of mix sets as well as having a strong sense of community rich in information and knowledge. A really great community worth joining.
 

The Mixing Bowl
The Mixing Bowl compiles mix sets from The Essential Mix, The Breezeblock, Worldwide, Back To The Basics, XFM, One World, Blue Room, Solid Steel. The Mixing Bowl also has some Rare DJ set and promos from various artists.
House, Trance, IDM, Breaks, Hard House, Techno, Drum & Bass, Hip-Hop, Big Beat, Trip-Hop & Turntablism.

dubstep
50+ nice mix sets. Mainly ripped from radio shows/stations RinseFM, Underground Knowledge, BBC Radio One, Pyro Radio, Peel Tribute Show, Dawntempo, Sao Paulo, 1XTRA, Breezeblock and Kiss100. Also has some nice Studio Mixes and Live Sets.
MasterMix dot org offline 16th august 2006
Mastermix dot org is the personal project of a man named Richcolor to encode all his hip hop and soul mixtapes into MP3 format. These are mostly London pirate radio recordings from the mid 1980's, an exciting and innovative era in radio history. Sets are recorded in bitrates you wouldn't write home about, but there are some fantasic sets in there.
LiveSets.com
Livesets.com is a huge electronic music community with over 53,000 members worldwide, a news portal and even a streaming internet radio station on which you can hear upcoming dj's, talents, well-known artists, live shows and party broadcasts from all around the globe.
PEARSON TOWERS - breezeblocks & essential mixes
A guy named Jon's personal website with some nice mixes by Shadow, Unkle, Krafty Kuts, Freestylers, Yoda & Greenpeace, The Avalanches, Freddy Fresh, Hexstatic, Lo Fidelity Allstars, RJD2, Unkle vs Scratch Perverts, Mr Scruff, and Steinski vs Plus One vs Jonathan Moore. Click on the 'mix sets' link.
UK Trance Alliance
UK Trance Alliance delivered the best trance dj mixes from the biggest DJs free of charge between 2003-2005. In 2006 they changed the site to start using torrents as well setting up a pay-for area. Technically they still offer some free mp3 sets to download but they make them difficult to find and there are no where as many as there used to be. Unfortunatly you are going to have to hunt around their site to find the mixsets.
Djmixes2k
Djmixes2k posts privately recorded livesets and mixes. The sets are constantly updated and stay online for 10 days. Unfortunatly you have to download and install 3rd party download software to download the mixsets.
Spirit Of House
A small collection of house mixes by Michael Fossati. Unfortunately the mixes are in low quality Real Audio format.